Chemical elements
  Carbon
    Isotopes
    Energy
    Production
    Application
    Physical Properties
    Chemical Properties
      Methane
      Ethylene
      Acetylene
      Coal-Gas
      Carbon Tetrafluoride
      Tetrafluoromethane
      Carbon Tetrachloride
      Tetrachloromethane
      Carbon Tetrabromide
      Tetrabromomethane
      Carbon Tetraiodide
      Tetraiodomethane
      Carbon Oxychloride
      Carbonyl Chloride
      Phosgene
      Carbon Oxybromide
      Carbonyl Bromide
      Carbon Suboxide
      Carbon Monoxide
      Carbon Dioxide
      Percarbonic Acid
      Carbamic Acid
      Carbamide
      Urea
      Carbon Disulphide
      Carbonyl Sulphide
      Carbon Oxysulphide
      Thiocarbonyl Chloride
      Thiocarbonic Acid
      Thiocarbamic acid
      Thiourea
      Thiocarbamide
      Perthiocarbonates
      Carbon Monosulphide
      Carbon Subsulphide
      Carbon Sulphidoselenide
      Carbon Sulphidotelluride
      Carbon Nitrides
      Cyanogen
      Dicyanogen
      Hydrocyanic Acid
      Prussic Acid
      Cyanogen Chloride
      Chlorocyanogen
      Cyanogen Bromide
      Bromocyanogen
      Cyanogen Iodide
      Iodocyanogen
      Polymerised Cyanogen Halides
      Cyanamide
      Cyanic Acid
      Cyanuric Acid
      Cyamelide
      Fulminic Acid
      Thiocyanic Acid
      Sulphocyanic Acid
      Isoperthiocyanic Acid
      Cyanogen Sulphide
      Thiocyanic Anhydride
    Diamonds
    Graphite
    Amorphous Carbon
    Coal

Cyanamide, CNNH2






Cyanamide, CN-NH2 is formed, according to a common way of preparing amides, by the action of ammonia on the chloride:

CNCl + 2NH3 = CNNH2 + NH4Cl;

it is also conveniently obtained from thiourea by the removal from it of H2S through the agency of precipitated mercuric oxide:

CS(NH2)2 + HgO = CNNH2 + HgS + H2O.

The mercuric oxide is added to an aqueous solution of thiourea until a drop of the liquid ceases to darken ammoniacal silver nitrate solution by formation of Ag2S. The filtered solution is then evaporated and extracted with ether, whence cyanamide crystallises.

Cyanamide melts at 40° C., and can be distilled at 143°-144° C. under 18 mm. pressure. It is deliquescent, is volatile in steam, and is converted by very dilute nitric acid into urea:

CNNH2 + H2O = CO(NH2)2.

Like the amides of other weak acids, cyanamide possesses both basic and acidic properties. The dihydrochloride, CNNH2.2HCl, is formed as a crystalline powder when hydrogen chloride gas is passed into an ethereal solution of cyanamide; on the other hand, the di-silver salt CN-NAg2 is precipitated as a yellow powder when ammoniacal silver nitrate is added to an aqueous solution of cyanamide. Likewise the monosodium salt CN-NHNa is formed when sodium ethoxide reacts with alcoholic cyanamide.

Calcium cyanamide mixed with carbon is produced, rather than calcium cyanide, when nitrogen is passed over calcium carbide heated in an electric furnace:

CaC2 + N2 = CN-NCa + C.

The product known as "Kalkstickstoff" or "Nitrolim" is employed as a nitrogenous manure.

Calcium cyanamide is hydrolysed by cold water with the formation of dicyanamide:

2CaN-NC + 4H2O = 2Ca(OH)2 + NH:C(NH2)(NH-CN)

When carbon dioxide is passed through this solution calcium cyanamidocarboxylate, , is produced.

Under the influence of heat cyanamide polymerises to dicyanamide, NH:C(NH2)(NHCN), and cyanuramide, (CN-NH2)3.


© Copyright 2008-2012 by atomistry.com