Chemical elements
  Carbon
    Isotopes
    Energy
    Production
    Application
    Physical Properties
    Chemical Properties
      Methane
      Ethylene
      Acetylene
      Coal-Gas
      Carbon Tetrafluoride
      Tetrafluoromethane
      Carbon Tetrachloride
      Tetrachloromethane
      Carbon Tetrabromide
      Tetrabromomethane
      Carbon Tetraiodide
      Tetraiodomethane
      Carbon Oxychloride
      Carbonyl Chloride
      Phosgene
      Carbon Oxybromide
      Carbonyl Bromide
      Carbon Suboxide
      Carbon Monoxide
      Carbon Dioxide
      Percarbonic Acid
      Carbamic Acid
      Carbamide
      Urea
      Carbon Disulphide
      Carbonyl Sulphide
      Carbon Oxysulphide
      Thiocarbonyl Chloride
      Thiocarbonic Acid
      Thiocarbamic acid
      Thiourea
      Thiocarbamide
      Perthiocarbonates
      Carbon Monosulphide
      Carbon Subsulphide
      Carbon Sulphidoselenide
      Carbon Sulphidotelluride
      Carbon Nitrides
      Cyanogen
      Dicyanogen
      Hydrocyanic Acid
      Prussic Acid
      Cyanogen Chloride
      Chlorocyanogen
      Cyanogen Bromide
      Bromocyanogen
      Cyanogen Iodide
      Iodocyanogen
      Polymerised Cyanogen Halides
      Cyanamide
      Cyanic Acid
      Cyanuric Acid
      Cyamelide
      Fulminic Acid
      Thiocyanic Acid
      Sulphocyanic Acid
      Isoperthiocyanic Acid
      Cyanogen Sulphide
      Thiocyanic Anhydride
    Diamonds
    Graphite
    Amorphous Carbon
    Coal

Carbon Monosulphide, CS






The first indication of the existence of the sulphur analogue of carbon monoxide was the observation of Losanitsch and Jovitschitsch that carbon disulphide is decomposed by the silent electric discharge in presence of hydrogen or carbon monoxide with the formation of a lower sulphide supposed to be CS; Thomsen also found that when nitrogen saturated with carbon disulphide vapour is passed repeatedly over heated copper, the copper removes some sulphur from the disulphide, leaving the monosulphide. More recently Dewar and H. O. Jones found that thiocarbonyl chloride reacts rapidly with nickel carbonyl at the ordinary temperature according to the equation:

xCSCl2 + xNi(CO)4 = xNiCl2 + 4xCO + (CS)x.

When nickel chloride is extracted by water from the solid product, a brown substance remains which by analysis is shown to have the empirical composition represented by the formula CS, but which, on account of its being a non-volatile solid, must be a polymer (CS)x. The same product was always obtained, although the conditions of its formation were varied, and after purification and drying it had a density of about 1.6 in the finely divided state and of 1.83 after compression.

Polymerised carbon monosulphide gives a purplish-brown solution with concentrated sulphuric acid, from which the unchanged substance is reprecipitated on pouring into water. Aqueous and alcoholic solutions of ammonia, ammonium sulphide, and potassium hydroxide, sulphide, and hydrosulphide, also give deep brown solutions from which the monosulphide is precipitated unchanged by acid. The solid is unchanged below 360° C. in a vacuum, but at a low red heat a change takes place in accordance with the equation:

2(CS)x = xC + xCS2.

When carbon disulphide is exposed for a long time to sunlight a red substance is obtained, which is supposed also to be a polymeric form of the monosulphide.

So far the nature of the simple substance CS had not been elucidated, but Dewar and Jones followed up this communication with another in which evidence was forthcoming of the formation of the non-polymerised monosulphide. Carbon disulphide vapour at low pressure was submitted to the action of the silent electric discharge, with the consequence that sulphur separated. When the resulting vapour was cooled in a tube immersed in liquid air and then brought again to the temperature of the atmosphere an explosion took place, and the brown substance previously identified as (CS)x was formed. It appears, therefore, that carbon monosulphide is an endothermic gas, condensible by means of liquid air, which rapidly polymerises to (CS)x at atmospheric temperature.


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